Three-phase junction for modulating electron–hole migration in anatase–rutile photocatalysts

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Three-phase junction for modulating electron-hole migration in anatase-rutile photocatalysts.

The heterophase solid-solid junction as an important type of structure unit has wide applications for its special mechanics and electronic properties. Here we present a first three-phase atomic model for the anatase-rutile TiO2 heterophase junction and determine its optical and electronic properties, which leads to resolution of the long-standing puzzles on the enhanced photocatalytic activity ...

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Three-phase junction for modulating electron–hole migration in anatase–rutile photocatalysts† †Electronic supplementary information (ESI) available: Optimized structures (XYZ coordinates) for pure phase and biphase crystals; other structure models for phase junction. See DOI: 10.1039/c5sc00621j

The heterophase solid–solid junction as an important type of structure unit has wide applications for its special mechanics and electronic properties. Here we present a first three-phase atomic model for the anatase–rutile TiO2 heterophase junction and determine its optical and electronic properties, which leads to resolution of the long-standing puzzles on the enhanced photocatalytic activity ...

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ژورنال

عنوان ژورنال: Chemical Science

سال: 2015

ISSN: 2041-6520,2041-6539

DOI: 10.1039/c5sc00621j